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Migratory insertion and hydrogenation of a bridging azide in a thiolate-bridged dicobalt reaction platform

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Indexed by:期刊论文

Date of Publication:2017-09-14

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、PubMed

Volume:53

Issue:71

Page Number:9854-9857

ISSN No.:1359-7345

Abstract:A novel well-defined thiolate-bridged dicobalt azido complex is converted to a rare sulfilimide-bridged dicobalt complex via nitrogen atom migratory insertion into the Co-S bond upon thermolysis. Intriguingly, the homolytic cleavage of hydrogen is achieved by this azide under mild conditions to furnish a partially hydrogenated azido complex.

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