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Indexed by:期刊论文

Date of Publication:2018-12-04

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE、Scopus

Volume:54

Issue:93

Page Number:13119-13122

ISSN No.:1359-7345

Abstract:Reduction of a thiolate-bridged (FeFeIII)-Fe-II complex leads to the cleavage of an Fe-S bond by the insertion of the methylene unit from CH2Cl2 to give a neutral (FeFeIII)-Fe-II complex with a novel Fe-CH2-S fragment. The structural and electrochemical differences of the alkylated and the non-alkylated Fe2S2 complexes are also examined.