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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：兰州大学
学位：博士
所在单位：化工学院
学科：有机化学. 药物化学. 精细化工
办公地点：西部校区化工实验楼G-413
联系方式：0411-84986190 15942819406
电子邮箱：bmwang@dlut.edu.cn
扫描关注
Methylene insertion into an Fe2S2 cluster: formation of a thiolate-bridged diiron complex containing an Fe-CH2-S moiety
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论文类型：期刊论文
发表时间：2018-12-04
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：SCIE、Scopus
卷号：54
期号：93
页面范围：13119-13122
ISSN号：1359-7345
摘要：Reduction of a thiolate-bridged (FeFeIII)-Fe-II complex leads to the cleavage of an Fe-S bond by the insertion of the methylene unit from CH2Cl2 to give a neutral (FeFeIII)-Fe-II complex with a novel Fe-CH2-S fragment. The structural and electrochemical differences of the alkylated and the non-alkylated Fe2S2 complexes are also examined.