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Indexed by:期刊论文

Date of Publication:2015-01-14

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、PubMed、Scopus

Volume:44

Issue:2

Page Number:475-479

ISSN No.:1477-9226

Abstract:Photocatalytic oxidation of organic compounds proceeded efficiently in a hybrid system with ruthenium aqua complexes as catalysts, BiVO4 as a light absorber, [Co(NH3)(5)Cl](2+) as a sacrificial electron acceptor and water as an oxygen source. The photogenerated holes in the semiconductor are used to oxidize molecular catalysts into the high-valent Ru-IV=O intermediates for 2e(-) oxidation.