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论文类型：期刊论文

发表时间：2016-10-01

发表刊物：CHEMPLUSCHEM

收录刊物：SCIE、Scopus

卷号：81

期号：10,SI

页面范围：1056-1059

ISSN号：2192-6506

关键字：dye-sensitized photoelectrochemical cells; host-guest systems; ruthenium; solar cells; water splitting

摘要：A ruthenium water oxidation catalyst (WOC) bearing hydrophobic ligands was incorporated on the surface of a dye-sensitized nanostructured TiO2 film by formation of a host-guest adduct with the dye. This provides a new strategy for constructing photocatalytically active electrodes for water oxidation. The resultant photoanode exhibits a photocurrent of 800Acm(-2) under visible-light illumination (>400nm, 300mWcm(-2)) and 240Acm(-2) under simulated sunlight illumination (AM 1.5G, 100mWcm(-2)) with an applied bias of 0.2V vs. NHE in neutral phosphate buffer.