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个人信息Personal Information
研究员
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：精细化工
办公地点：大连理工大学西部校区E-302
电子邮箱：lifei@dlut.edu.cn
Electrocatalytic water oxidation by a macrocyclic Cu(II) complex in neutral phosphate buffer
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论文类型：期刊论文
发表时间：2016-08-16
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：SCIE、PubMed
卷号：52
期号：68
页面范围：10377-10380
ISSN号：1359-7345
摘要：A single-site copper complex, [Cu(TMC)(H2O)](NO3)(2) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was found to be the most active copper-based catalyst towards electrocatalytic water oxidation in neutral aqueous solution. Complex 1 leads to a cathodic shift of approximately 200 mV in potential to reach a current density of 1 mA cm(-2) in comparison with that of the previously reported dinuclear copper complex under the same conditions. Upon immobilization of complex 1 on carbon cloth, it shows greatly improved activity than other copper-based WOCs including CuOx and Cu2+.