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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工国家重点实验室，副主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼F-212A
联系方式：0411-84986249
电子邮箱：dr.gaoyan@dlut.edu.cn
Synthesis and photophysical and electrochemical properties of a binuclear Ru(bpy)(3)-Cu(III) corrole complex
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论文类型：期刊论文
发表时间：2007-01-01
发表刊物：JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
收录刊物：SCIE
卷号：11
期号：5-6
页面范围：463-469
ISSN号：1088-4246
关键字：Cu(III) corrole; [Ru(bpy)(3)](2+); OEC; photosystem II; water oxidation
摘要：A novel binuclear Ru-Cu complex, composed of a copper(III)-corrole and a ruthenium(II) tris(bipyridine) moicty linked by an amide bond, has been synthesized and characterized by H-1 NMR, UV-vis and mass spectrometry. The steady-state emission and the electrochemical properties were investigated. Compared to the parent [Ru(bpy)(3)](2+), the emission-of the desired complex was substantially quenched when the MLCT of [Ru(bpy)(3)](2+) was selectively photoexcited. Copyright (C) 2007. Society of Porphyrins & Phthalocyanines.