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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工国家重点实验室，副主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼F-212A
联系方式：0411-84986249
电子邮箱：dr.gaoyan@dlut.edu.cn
扫描关注
Synthesis and characterisation of a high valent dinuclear Mn(III,III) complex of a triphenolate ligand [N4O3](3-) with two extra functional groups
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论文类型：期刊论文
发表时间：2004-01-01
发表刊物：JOURNAL OF CHEMICAL RESEARCH-S
收录刊物：SCIE
期号：1
页面范围：57-58
ISSN号：0308-2342
关键字：dinuclear manganese; ligand design; artificial photosynthesis
摘要：A new high valent complex [Mn-2(III,III)L(mu-OAc)(2)].PF6 7 was prepared, where L was the tri-anion of 2,6-Bis {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl}-4-methylphenol which contained two additional phenolate groups and two tert-butyl groups compared to its parent [Mn-2(II, II)(bpmp)(mu-OAc)(2)].PF6. These improvements narrowed the disparity between the new model and (Mn)(4) cluster (OEC in nature).