高岩

个人信息Personal Information

教授

博士生导师

硕士生导师

任职 : 精细化工国家重点实验室,副主任

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工

办公地点:大连理工大学西部校区化工实验楼F-212A

联系方式:0411-84986249

电子邮箱:dr.gaoyan@dlut.edu.cn

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Synthesis and characterization of manganese and copper corrole xanthene complexes as catalysts for water oxidation

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论文类型:期刊论文

发表时间:2007-02-26

发表刊物:TETRAHEDRON

收录刊物:SCIE

卷号:63

期号:9

页面范围:1987-1994

ISSN号:0040-4020

关键字:metal corrole complex; synthesis; electrochemistry; oxygen evolution

摘要:Two corrole xanthene ligands and four corresponding Mn-IV and Cu-III complexes have been synthesized and spectroscopically characterized. This kind of complexes, comprising of xanthene and corrole linked by an amide bond, were designed as bio-inspired models for the oxygen evolving complex (OEC) in Photosystem II. We find that both manganese complexes 4a and 5a have efficiency on catalyzing oxygen evolution at low potential (about 0.80 V) by electrochemical method, which is a significant progress in the study of dioxygen formation. (c) 2006 Elsevier Ltd. All rights reserved.