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论文类型：期刊论文

发表时间：2014-12-10

发表刊物：ELECTROCHIMICA ACTA

收录刊物：SCIE、Scopus

卷号：149

页面范围：337-340

ISSN号：0013-4686

关键字：photoanode; molecular device; photoelectrochemical cell; water splitting

摘要：An efficient two-electrode molecular PEC was assembled, in which a photoanode was constructed using a co-adsorbed method with a molecular photosensitizer (PS) 1 and a molecular catalyst 2 on TiO2-sintered FTO electrode (TiO2(1 + 2)). Without applied bias against a reference electrode, the system achieves remarkable photocurrent densities and carries out light driven water oxidation as evidenced by Clark electrode measurements in solution. A photocurrent density of 70 mA/cm(2) has been obtained within 10 s illumination time, and a TON of about 220 was obtained with a maximum turnover frequency (TOF) of ca. 4 min(-1) within the initial 5 minutes illumination duration. (C) 2014 Elsevier Ltd. All rights reserved.