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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工国家重点实验室，副主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼F-212A
联系方式：0411-84986249
电子邮箱：dr.gaoyan@dlut.edu.cn
Synthesis of Tyrosine-involved Corrole Cu(III), Mn(IV), and Mn(III) Complexes As Biomimetic Models of Oxygen Evolving Complex in Photosystem II
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论文类型：期刊论文
发表时间：2014-12-01
发表刊物：RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
收录刊物：SCIE、Scopus
卷号：88
期号：13
页面范围：2486-2492
ISSN号：0036-0244
关键字：Cu(III) corrole; Mn(IV) corrole; Mn(III) corrole; tyrosine; OEC
摘要：Boc-protected tyrosine-attached corrole ligand on the "ortho" position compound 3, its corresponding copper (III) 4a, manganese (IV) 4b, and manganese (III) 4c complexes have been designed and synthesized based on the structures of active-centers of related biological systems. H-1 NMR and electronic absorption spectra of these metal complexes are investigated. The crystal structure of 4a displays the relative position of TyrOH unit to the high valent metal center. Electrochemistry investigations display the possibilities of intramolecular electron or energy transfer between TyrOH group and metal corrole group.