Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-05-01

Journal: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Included Journals: Scopus、SCIE

Volume: 638

Issue: 6

Page Number: 1006-1011

ISSN: 0044-2313

Key Words: Supramolecular chemistry; Coordination polymers; Self-assembly; Sulfonate; Coordination modes

Abstract: A rigid imidazolate/sulfonate functionalized ligand, 6-(4-sulfonatopheny)imidazo[4, 5-f]isoindole-5, 7-dione (SPID) was designed and used for assembling reactions with Mn2+ and Cu2+ ions. Two 2D frameworks compounds, [Mn(H-1SPID)2(DMAC)2] (1) and [Cu(H-2SPID)(H2O)2]center dot 0.7DMAC center dot 0.3H2O (2) (DMAC = N,N-dimethylacetamide) were obtained. Single crystal X-ray analyses show that 1 has a 2D (4, 4)-net based on 4-connected Mn2+ nodes and mu 2-coordinated H-1SPID spacers, whereas compound 2 has a 2D (6, 3)-net built of 3-connected Cu2+ nodes and mu 3-coordinated H-2SPID spacers. Additionally, the thermal behavior of 1 and 2 is presented.