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Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)(2)(ClO4)(2)](2-) clusters and slow relaxation of magnetization

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-11-21

Journal: DALTON TRANSACTIONS

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 41

Issue: 43

Page Number: 13264-13266

ISSN: 1477-9226

Abstract: With formate as ligand, two 1-D 3d-4f compounds (linear and zigzag) based on pyramidal {TbCu4} unit were obtained. Chair-like [( H2O)(2)(ClO4)(2)](2-) clusters and mu(5)-eta(1):eta(4) bridging mode of formate were observed in the linear one which also displays slow relaxation of the magnetization.

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