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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 日本东北大学金属材料研究所 客座教授 日本城西国际 客座教授
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：材料科学与工程学院
学科：材料学. 材料加工工程. 材料物理与化学
办公地点：大连理工大学材料学院
联系方式：0411-84706063 http://anam.dlut.edu.cn
电子邮箱：wzhang@dlut.edu.cn
Highly Selective Semihydrogenation of Alkynes to Alkenes by Using an Unsupported Nanoporous Palladium Catalyst: No Leaching of Palladium into the Reaction Mixture
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论文类型：期刊论文
发表时间：2017-12-01
发表刊物：ACS CATALYSIS
收录刊物：SCIE、EI
卷号：7
期号：12
页面范围：8296-8303
ISSN号：2155-5435
关键字：alkyne; semihydrogenation; heterogeneous catalysis; nanoporous palladium; no leaching
摘要：We report the highly chemoselective and stereoselective semihydrogenation of alkynes to Z-internal and terminal alkenes by using unsupported nanoporous palladium (PdNPore) as a heterogeneous catalyst under mild reaction conditions (room temperature and 1 atm of H-2). The semihydrogenation of various terminal/internal and aromatic/aliphatic alkynes afforded the corresponding alkenes in good chemical yields with high selectivities. PdNPore further showed high chemoselectivity toward terminal alkynes in the presence of internal alkynes, which has not yet been achieved using supported palladium nanoparticle catalysts. H-H heterolysis of H-2 on the surface of PdNPore was strongly suggested by deuterium labeling experiments. No Pd leached from PdNPore during the reaction, and the catalyst was easily recovered and reused without a loss of activity.