个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:哈尔滨工业大学
学位:博士
所在单位:材料科学与工程学院
学科:材料加工工程
办公地点:铸造中心101
联系方式:0411-84706220
电子邮箱:jiejc@dlut.edu.cn
First-principles study of hydrogen incorporation into the MAX phase Ti3AlC2
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论文类型:期刊论文
发表时间:2016-04-27
发表刊物:INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
收录刊物:SCIE、EI
卷号:41
期号:15
页面范围:6387-6393
ISSN号:0360-3199
关键字:First-principles calculations; Hydrogen storage; Diffusion; Vacancies
摘要:First-principles calculations have been performed to study hydrogen incorporation into the MAX phase Ti3AlC2. It is found that H atoms are thermally favorable to be incorporated into the interstitial sites of Ti-Al layers in stoichiometric Ti3AlC2. Only when C vacancies exist, H atoms can be incorporated into Ti-C layers. In Ti-Al layers, the hexagonal interstitial site (I-hexa) consisting of three Al atoms and two Ti atoms, the tetrahedral interstitial site (L-tetr-2) consisting of one Al atom and three Ti atoms, and the octahedral interstitial site (I-oct-3) consisting of three Ti atoms and three Al atoms are all possible sites for H incorporation. Among them, I-tetr-2 is the most stable one, followed by I-oct-3 and the last one is I-hexa sites. The linear synchronous transit optimization study shows that the diffusion of H in the Ti-Al layers is feasible which could be helpful for the continuous insertion and the following extraction of H in Ti3AlC2. Copyright (C) 2016, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.