Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.
Release Time:2019-03-11 Hits:
Indexed by: Journal Article
Date of Publication: 2018-02-21
Journal: Molecules (Basel, Switzerland)
Included Journals: PubMed、SCIE
Volume: 23
Issue: 2
ISSN: 1420-3049
Key Words: Lewis pair polymerization,block copolymers,brush copolymers,click reaction,organocatalytic ring-opening polymerization
Abstract: Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide.
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