location: Current position: Home >> Scientific Research >> Paper Publications

Highly efficient conversion of CO2 to cyclic carbonates with a binary catalyst system in a microreactor: intensification of "electrophile-nucleophile" synergistic effect

Hits:

Indexed by:期刊论文

Date of Publication:2018-01-01

Journal:RSC ADVANCES

Included Journals:SCIE

Volume:8

Issue:68

Page Number:39182-39186

ISSN No.:2046-2069

Abstract:An intensification of the electrophile-nucleophile synergistic effect was achieved in a microreactor for the coupling reaction of CO2 and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope.

Pre One:Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.

Next One:Fe(Ⅲ)-salan配合物催化羰基硫与环氧烷烃交替共聚