Release Time:2019-03-09  Hits:

Indexed by:Journal Article

Date of Publication:2010-11-05

Journal:ORGANIC LETTERS

Included Journals:Scopus、PubMed、SCIE

Volume:12

Issue:21

Page Number:4748-4751

ISSN:1523-7060

Summary:A highly selective synthesis of a variety of functionalized allylic 2-alkynoates was realized via the carboxylative coupling of terminal alkynes, allylic chlorides, and CO2 catalyzed by the N-heterocyclic carbene copper(I) complex (IPr)CuCl. The catalyst can be easily recovered without any loss in activity and product selectivity.