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论文类型：期刊论文

发表时间：2022-06-30

发表刊物：Jingxi Huagong/Fine Chemicals

卷号：38

期号：10

页面范围：2072-2080

ISSN号：1003-5214

摘要：A series of PdZnx/Al2O3 bimetallic catalysts with different molar ratios of Pd to Zn were prepared in a controlled manner by strong electrostatic adsorption for the selective hydrogenation of 1,4-butynediol (BYD), and the effect of Zn on the catalytic hydrogenation was investigated. It was found that introducing a small amount of Zn was able to maintain high activity of the catalyst and greatly improve its selectivity for the intermediate cis-1,4-butenediol (cis-BED). PdZn2/Al2O3 catalyst exhibited high catalytic activity with 91% conversion and selectivity for cis-BED (86%) under the conditions of 50 ℃, 1 MPa H2 pressure, and contact time of 6 gcat•h/mol. In addition, temperature-programmed reduction and X-ray photoelectron spectroscopy results showed that the precursor was calcined at 400 ℃ and reduced at 400 ℃ to form the PdZn bimetallic catalyst. The doping of Zn atoms effectively modulated the geometrical and electronic effects of the Pd active sites, which effectively inhibited the over-hydrogenation of the intermediate products. © 2021, Editorial Office of FINE CHEMICALS. All right reserved.

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