论文名称:Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane 论文类型:期刊论文 发表刊物:CHEMICAL COMMUNICATIONS 收录刊物:SCIE 卷号:52 期号:44 页面范围:7082-7085 ISSN号:1359-7345 摘要:We presented the immobilization of ionic liquids on the channel walls of COFs using a post-synthetic strategy. The ionic [Et4NBr](50%)-Py-COF afforded a high CO2 adsorption capacity of 164.6mg g(-1) (1 bar, 273 K) and was developed as an effective heterogeneous catalyst for the transformation of CO2 into value-added formamides under ambient conditions. 发表时间:2016-01-01