Release Time:2019-03-09  Hits:

Indexed by: Journal Papers

Date of Publication: 2015-03-07

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、SCIE、PubMed

Volume: 51

Issue: 19

Page Number: 4013-4016

ISSN: 1359-7345

Abstract: A nonheme manganese(IV)-oxo complex, [Mn-IV(O)(BQCN)](2+), was generated in the photochemical and chemical oxidation of [Mn-II(BQCN)](2+) with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [Mn-II(BQCN)](2+) has been demonstrated in both neutral and acidic media.