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论文类型：期刊论文

发表时间：2020-05-01

发表刊物：CHEMICAL ENGINEERING JOURNAL

收录刊物：EI、SCIE

卷号：387

ISSN号：1385-8947

关键字：Magnolol; Biomass; Epoxy resin; Intrinsic flame retardancy; High performance

摘要：Development of sustainable bio-based epoxy resins having better comprehensive properties than available petroleum-based epoxy resins is of paramount importance for alleviation of energy pressure and enrichment of the potent category of high-performance epoxy resins. In this study, a fully bio-based epoxy resin precursor (DGEM) was synthesized from a naturally occurring magnolol through a highly efficient one step process. The bio-based epoxy resin obtained was then cured with 4, 4'-diaminodiphenyl sulfone (DDS) and compared to the petroleum-based commercial diglycidylether of bisphenol A (DGEBA). After curing with DDS, DGEM/DDS showed higher glass transition temperature than DGEBA/DDS which was 279 degrees C and 231 degrees C, respectively. The char yield (in N-2), storage modulus and flexural modulus of the former were 1.9-fold, 47.5%, and 41.3% higher than those of the latter, respectively. Interestingly, bio-based epoxy resin of DGEM exhibited excellent processability with extremely low viscosity of 0.155 Pa.s at room temperature and a broader processing window than DGEBA/DDS as well. To exhibit such an excellent processability is very rare for high-performance epoxy resins. In addition, the cured DGEM/DDS also showed outstanding intrinsic flame retardancy, which passed the V-0 rate of UL-94 test. This study offers an opportunity to prepare bio-based epoxy resins with better properties than DGEBA and exhibits great promise in cuffing-edge applications.