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论文类型：期刊论文

发表时间：2020-03-01

发表刊物：APPLIED MATERIALS TODAY

收录刊物：EI、SCIE

卷号：18

ISSN号：2352-9407

关键字：Conjugated microporous polymers; Nanosheet; Radical polymerization; Stability; Photocatalysis

摘要：The challenge of light-driven controlled radical polymerization through non-noble metal catalyst remains the most significant issue. Ferrocene-bearing microporous aromatic polymer nanosheets (termed "FeMAP-11") that feature high chemical stability were reported here to synergistically combine the advantageous properties of the redox-active ferrocene units and the conjugated microporous polymers (CMPs), and to be able to serve as photocatalyst for activators regenerated by electron transfer atom transfer radical polymerization (AGET-ATRP). It succeeded in initiating polymerizations of 3 common vinyl monomers, i.e. methyl methacrylate (MMA), methacrylate (MA) and styrene (St), and produced polymers with controlled molecular weight and relatively low molecular weight dispersity ((1) over tilde .3). Benefiting from steric hindrance through ketone-amine chemistry, the microporous catalyst with tolerance to acidic and basic media was found stable under the AGET-ATRP conditions. It showed negligible metal leaching and good recyclability for at least 10 cycles without sacrifice of its catalytic performance. Our tests proved that FeMAP-11 exceeded the state-of-the-art ATRP photocatalysts such as UiO-66-NH2, titanium MOF-901 and the commercial P-25 Titania, demonstrating promising potential in catalysis in view of green chemistry. (C) 2019 Elsevier Ltd. All rights reserved.