丁保君

个人信息Personal Information

副教授

硕士生导师

主要任职:无

性别:女

毕业院校:东北师范大学

学位:硕士

所在单位:化学学院

学科:分析化学

办公地点:大连理工大学西部校区知化楼

联系方式:dingbj@dlut.edu.cn

电子邮箱:dingbj@dlut.edu.cn

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A quinoline-functionalized amphiphilic fluorogenic probe for specific detection of trivalent cations

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论文类型:期刊论文

发表时间:2014-01-01

发表刊物:RSC ADVANCES

收录刊物:SCIE、EI、Scopus

卷号:4

期号:87

页面范围:46955-46961

ISSN号:2046-2069

摘要:A novel fluorescent probe, which has an amphiphilic structure and can selectively detect and distinguish trivalent metal cations, was synthesized. The probe has a hydrophobic quinoline head and a hydrophilic pyridinium tail. This amphiphilic molecular structure makes the molecule exhibit ideal solubility and sensitivity in three kinds of solvents, including EtOH, CH3CN and H2O. The ideal cross-reactivity of this probe in different solvents provided it with the ability to distinguish Fe3+, Cr3+, Al3+, Ru3+ and Au3+ through the PCA method. The detection limits of the probe for trivalent metal cations reach the micromolar range.