丁保君

个人信息Personal Information

副教授

硕士生导师

主要任职:无

性别:女

毕业院校:东北师范大学

学位:硕士

所在单位:化学学院

学科:分析化学

办公地点:大连理工大学西部校区知化楼

联系方式:dingbj@dlut.edu.cn

电子邮箱:dingbj@dlut.edu.cn

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A heptanuclear heterotrimetallic [Na2Cr2Tb3] cluster exhibiting single-molecule magnet behavior

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论文类型:期刊论文

发表时间:2013-11-01

发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS

收录刊物:SCIE、Scopus

卷号:37

页面范围:202-205

ISSN号:1387-7003

关键字:Heptanuclear; Heterotrimetallic; Maleic acid; Bicapped trigonal bipyramid; Slow relaxation of the magnetization

摘要:With maleic acid as the ligand, a heterotrimetallic cluster {[Na(H2O)][Na2Cr2Tb3(mu(3)-OH)(6)(L)(6)(H2O)(17)]}center dot 16H(2)O (H2L = maleic acid) (1) bearing a bicapped trigonal bipyramidal [Na2Cr2Tb3] metal skeleton was synthesized and characterized. Magnetic measurements indicate that 1 displays overall ferromagnetic interactions and slow relaxation of the magnetization. (C) 2013 Elsevier B.V. All rights reserved.