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Wet cation exchange route to semiconductor alloys: the case study of MgxZn1-xO

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Li, Keyan
通讯作者:
Xue, DF (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
合写作者:
Yan, Pengcheng,Zhang, Chengbo,Xue, Dongfeng
发表时间:
2013-01-01
发表刊物:
INTERNATIONAL JOURNAL OF NANOTECHNOLOGY
收录刊物:
SCIE、EI、Scopus
文献类型:
J
卷号:
10
期号:
1-2
页面范围:
22-29
ISSN号:
1475-7435
关键字:
cation exchange; Mg(x)Zn(1-x)Oalloy; band gap; UV-visible absorption
摘要:
We developed a novel cation exchange method to prepare the alloyed semiconductors. A series of self- assembled magnesium doped zinc oxide (MgxZn1-xO) particles were synthesised by varying the molar ratios of Mg precursor Mg-5(CO3)(4)(OH)(2)center dot 4H(2)O to Zn precursor ZnAc2 center dot 4H(2)O from 1: 1 to 3: 1 at different cation exchange time. Powder X-ray Diffraction (XRD) indicates that the samples are a mixture of hexagonal and cubic phases. The UV-visible (UV-vis) absorption spectra show that the band gap of MgxZn1-xO particles can be readily tuned by optimising the cation exchange time and the molar ratio of precursors. The morphology of MgxZn1-xO particles was observed by Scanning Electron Microscopy (SEM).
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