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Two-Phase Route to High Quality ZnO Quantum Dots with High Stability of Dispersity, Structure and Optical Properties

发表时间:2019-03-09
点击次数:
论文类型:
期刊论文
第一作者:
Zhang, Chengbo
通讯作者:
Xue, DF (reprint author), Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Peoples R China.
合写作者:
Li, Keyan,Song, Shuyan,Xue, Dongfeng
发表时间:
2012-11-01
发表刊物:
SCIENCE OF ADVANCED MATERIALS
收录刊物:
SCIE、Scopus
文献类型:
J
卷号:
4
期号:
11
页面范围:
1148-1153
ISSN号:
1947-2935
关键字:
ZnO Quantum Dots; Two-Phase Route; Surface Modification; Dispersity
摘要:
A two-phase system methanol-hexane is developed in the current work. These colloidal ZnO quantum dots (QDs) emission with yellow prepared by a traditional sol gel approach can realize surface modification with oleic acid (OA) via the two-phase route. The Pearson's Hard and Soft [Lewis] Acid and Base Principle together with the effect of microemulsion determines the OA capping on ZnO QDs. These ZnO QDs after surface modification with OA are highly stable in structure and optical properties as well as dispersity. This two-phase route successfully inhibits ZnO QDs from turning to acetate anion intercalated Zn based hydroxyl double salts. The visible emission intensity of these ZnO QDs after surface modification is unchanged as time went on. The dispersity of these ZnO QDs after surface modification is improved greatly and these ZnO QDs after surface modification can be stable in non-polar solvents for a long time.
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