Enantioselective iridium-catalyzed allylation of sodium benzotriazolide: an efficient way to chiral allylbenzotriazoles
发表时间：2019-03-09
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- 论文类型：
- 期刊论文
- 第一作者：
- Zhang, Min
- 通讯作者：
- Zhao, XM (reprint author), Tongji Univ, Dept Chem, 1239 Siping Rd, Shanghai 200092, Peoples R China.
- 合写作者：
- Guo, Xin-Wen,Zheng, Sheng-Cai,Zhao, Xiao-Ming
- 发表时间：
- 2012-12-19
- 发表刊物：
- TETRAHEDRON LETTERS
- 收录刊物：
- SCIE、Scopus
- 文献类型：
- J
- 卷号：
- 53
- 期号：
- 51
- 页面范围：
- 6995-6998
- ISSN号：
- 0040-4039
- 关键字：
- Sodium benzotriazolide; Iridium; Phosphoramidite ligand; Asymmetric allylation
- 摘要：
- A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl](2)/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioen-riched allylbenzotriazole compounds with up to 98% ee. (C) 2012 Elsevier Ltd. All rights reserved.
- 是否译文：
- 否
