Iridium-catalyzed enantioselective allylation of sodium 2-aminobenzenethiolate: an access to chiral benzo-fused N,S-heterocycles
发表时间：2019-03-09
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- 论文类型：
- 期刊论文
- 第一作者：
- Gao, Ning
- 通讯作者：
- Zhao, XM (reprint author), Tongji Univ, Dept Chem, 1239 Siping Rd, Shanghai 200092, Peoples R China.
- 合写作者：
- Guo, Xin-Wen,Zheng, Sheng-Cai,Yang, Wei-Kang,Zhao, Xiao-Ming
- 发表时间：
- 2012-11-18
- 发表刊物：
- TETRAHEDRON
- 收录刊物：
- SCIE、Scopus
- 文献类型：
- J
- 卷号：
- 68
- 期号：
- 46
- 页面范围：
- 9413-9418
- ISSN号：
- 0040-4020
- 关键字：
- Allylation; Iridium; Phosphoramidite ligand; Sodium 2-aminobenzenethiolate; Benzo-fused N,S-heterocycle
- 摘要：
- The use of sodium 2-aminobenzenethiolate in the enantioselective iridium catalyzed allylic substitution with a range of methyl allyl carbonates allows the concise synthesis of the branch-type products with both excellent regio- and enantioselectivities, which are functionalized N,S-containing allylic intermediates for the formation of chiral benzo-fused N,S-heterocycles. (C) 2012 Elsevier Ltd. All rights reserved.
- 是否译文：
- 否
