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Synthesis of Silica Nanotubes with Orientation Controlled Mesopores in Porous Membranes via Interfacial Growth

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Zhang, Anfeng
通讯作者:
Guo, XW (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
合写作者:
Hou, Keke,Gu, Lin,Dai, Chengyi,Liu, Min,Song, Chunshan,Guo, Xinwen
发表时间:
2012-03-27
发表刊物:
CHEMISTRY OF MATERIALS
收录刊物:
SCIE、EI、Scopus
文献类型:
J
卷号:
24
期号:
6
页面范围:
1005-1010
ISSN号:
0897-4756
关键字:
silica nanotube; mesoporous film; mesopore orientation; perpendicular; interfacial growth
摘要:
Silica nanotubes with mesopores perforating the wall were synthesized on the channel surface of porous anodic alumina (PAA) or polycarbonate membranes via interfacial growth. Transmission and scanning electron microscopy characterizations indicated that the mesopore orientation can be regulated from perpendicular to the wall to circling the axis when the thickness of the silica nanotube wall increases from about 15 to 40-60 nm, without any modification of the channel surface or external forces, just by optimizing the amount of the tetraethoxysilane confined in the channels of PAA. Mesopores in the silica nanotube wall arrange hexagonally when the diameter of the silica nanotubes is larger than 200 nm.
是否译文:

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