Eley-Rideal mode of formamide species formation in selective catalytic reduction of NOx by C2H2 over ferrierite based catalysts
发布时间：2019-03-10
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- 论文类型：
- 期刊论文
- 发表时间：
- 2008-06-30
- 发表刊物：
- CATALYSIS COMMUNICATIONS
- 收录刊物：
- EI、SCIE
- 文献类型：
- J
- 卷号：
- 9
- 期号：
- 11-12
- 页面范围：
- 2117-2120
- ISSN号：
- 1566-7367
- 关键字：
- nitric oxide; selective catalytic reduction; ferrierite; C2H2 Eley-Rideal mode
- 摘要：
- It is found that formamide species as a crucial intermediate of the selective catalytic reduction of NO by C2H2 Was produced by nitrate species reacting with acetylene in Eley-Rideal mode on H-ferrierite (HFER) based catalyst. The mode concerning the formamide intermediate formation was proposed for the first time in selective catalytic reduction of NO by hydrocarbons. Impregnation of 2% zirconium into HFER considerably favored the formation of formamide species, and therefore better catalytic activity for the title reaction was obtained on 2%Zr/HFER. (C) 2008 Elsevier B.V. All rights reserved.
- 第一作者
- Xing, Na
- 合写作者
- Guo, Xinwen,Zhang, Anfeng,Liu, Zhiguang,Wang, Xinping
- 通讯作者
- Wang, XP (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, POB 288,Linggong Rd 2, Dalian 116024, Peoples R China.