Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea plus hydrogen peroxide as oxidizing agent
发布时间：2019-03-10
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- 论文类型：
- 期刊论文
- 发表时间：
- 2008-04-25
- 发表刊物：
- JOURNAL OF CATALYSIS
- 收录刊物：
- EI、SCIE
- 文献类型：
- J
- 卷号：
- 255
- 期号：
- 2
- 页面范围：
- 343-346
- ISSN号：
- 0021-9517
- 关键字：
- epoxidation; propylene; propylene oxide; urea; hydrogen peroxide; titanium silicate-1; electron paramagnetic resonance
- 摘要：
- We compared the efficacies of urea + hydrogen peroxide (U+HP) and hydrogen peroxide (HP) as an oxidizing agent in the epoxidation of propylene catalyzed by a titanium silicate-1 (TS-1) molecular sieve. The TS-1 catalyst exhibited good performance and stability in the TS-1/(U+HP) system. EPR results showed that more active Ti-superoxo species led to better performance of TS-1 in the TS-1/(U+HP) system than in the TS-1/HP system. (c) 2008 Elsevier Inc. All rights reserved.
- 第一作者
- Cheng, Weiguo
- 合写作者
- Li, Gang,Guo, Xinwen,Zhang, Suojiang,Wang, Xiangsheng
- 通讯作者
- Cheng, WG (reprint author), Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, 1 Beiertiao Zhongguancun, Beijing 100080, Peoples R China.