贺高红

个人信息Personal Information

教授

博士生导师

硕士生导师

任职 : 精细化工全国重点实验室主任,教育部智能材料化工前沿科学中心执行主任,大连理工大学膜科学与技术研究开发中心主任

性别:女

毕业院校:中国科学院大连化物所

学位:博士

所在单位:化工学院

学科:化学工程. 膜科学与技术. 生物医学工程

联系方式:hgaohong@dlut.edu.cn

电子邮箱:hgaohong@dlut.edu.cn

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Covalent/ionic co-crosslinking constructing ultra-densely functionalized ether-free poly(biphenylene piperidinium) amphoteric membranes for vanadium redox flow batteries

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论文类型:期刊论文

发表时间:2020-11-01

发表刊物:ELECTROCHIMICA ACTA

卷号:359

ISSN号:0013-4686

关键字:Redox flow battery; Amphoteric membrane; Amphoteric-side-chain; Aryl ether bonds; Covalent/ionic co-crosslinking construction

摘要:A novel covalently/ionically co-crosslinked poly(biphenylene piperidinium) amphoteric membrane was designed for improved stability and efficiencies in vanadium redox flow batteries (VRFB). The amphotericside-chain structure provides an ultrahigh functionalization degree (4.93 mmol g(-1)) and unobstructed ion channels, which endowed the membrane with an excellent ion conduction capacity comparable to Nafion 212 (area resistance: 0.23-0.29 Omega.cm(2)). Surpassing traditional sulfonated membranes and single ionic crosslinked membranes, even at high level functionalization, the covalently/ionically co-crosslinking structures guaranteed the membrane a low swelling ratio (10.1%) and VO2+ permeability of 0.79 x 10(-8) cm(2).s(-1). Moreover, due to the lack of sensitive aryl ether bonds, these membranes showed very good chemical stability, with a slight mass loss of 3.43% (nearly 5.5 times lower than SPEEK) after soaking in vanadium oxygen species for 30 days. On this basis, the membrane exhibited excellent battery performance. The Coulombic, voltage, and energy efficiencies of a battery using the above membrane reached 98.12, 87.27, and 85.98% at 120 mA cm(-2) current density and no obvious decline occurred after 400 cycles. The self-discharge time of battery up to 136 h. These observations indicated that this membrane appeared very promising for use in VRFB applications. (C) 2020 Elsevier Ltd. All rights reserved.