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论文类型：期刊论文

发表时间：2014-04-07

发表刊物：CHEMICAL ENGINEERING SCIENCE

收录刊物：SCIE、EI、Scopus

卷号：107

页面范围：245-255

ISSN号：0009-2509

关键字：Membranes; Design; Separations; Carbon dioxide; Free energy change; Framework

摘要：Thermodynamic analysis can discern those energy requirements which might be decreased in the separation system. In this work a theoretical model based on nonequilibrium thermodynamics was established to analyze the free energy change and the key points governing separation efficiency in gas membrane separation. Mass transfer in membranes was treated to be a two-step process in the model: species selectively permeate across membrane to form a series of local permeate gases, then the local permeate gases converge into a bulk permeate stream. Thus the total work required by the membrane process was identified as (i) the work to drive mass permeation, (ii) the work wasted by permeate mixing, and (iii) the minimum separation work. The analysis of two typical systems - the recycle membrane cascade (RMC) and the continuous membrane column (CMC) - revealed that the work wasted by permeate mixing seriously affects the free energy efficiency. This work wastage can be reduced by retrofitting process frameworks. Subsequently, the analysis was used to identify the serious work-losing stages in the RMC. Finally, a partially retrofitted RMC was proposed with tangible reductions in both equipment investment and energy consumption. (C) 2013 Elsevier Ltd. All rights reserved