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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工全国重点实验室主任，教育部智能材料化工前沿科学中心执行主任，大连理工大学膜科学与技术研究开发中心主任
性别：女
毕业院校：中国科学院大连化物所
学位：博士
所在单位：化工学院
学科：化学工程. 膜科学与技术. 生物医学工程
联系方式：hgaohong@dlut.edu.cn
电子邮箱：hgaohong@dlut.edu.cn
Montmorillonite-Reinforced Sulfonated Poly(phthalazinone ether sulfone ketone) Nanocomposite Proton Exchange Membranes for Direct Methanol Fuel Cells
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论文类型：期刊论文
发表时间：2014-02-05
发表刊物：JOURNAL OF APPLIED POLYMER SCIENCE
收录刊物：SCIE、EI、Scopus
卷号：131
期号：3
ISSN号：0021-8995
关键字：clay; membranes; swelling; inorganic polymers; batteries and fuel cells
摘要：To produce a composite membrane with high conductivity and low permeability, SPPESK with a degree of sulfonation of 101% was carefully selected for the preparation of montmorillonite (MMT)-reinforced SPPESK using solution intercalation. The fundamental characteristics such as water uptake, swelling ratio, proton conductivity, methanol permeability, and mechanical properties of the composite membranes were studied. Water uptake is improved when organic MMT (OMMT) loading increase. The composite membranes with CTAB-MMT loading of 4-0.5% show 0.143-0.150 S cm(-1) proton conductivity at 80 degrees C, which approaches the value of Nafion112. In addition, methanol permeability was decreased to 6.29 x 10(-8) cm(2) s(-1) by the addition of 6 wt % OMMT. As a result, the SPPESK-MMT composite membrane is a good candidate for use in direct methanol fuel cells. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39852.