Densities of CO2/N-2/O-2 ternary mixtures at temperatures from (300.15 to 353.15) K and pressures from (5 to 18) MPa

论文类型：

期刊论文

第一作者：

Zhao, Changzhong

通讯作者：

Zhang, Y (reprint author), Dalian Univ Technol, Sch Energy & Power Engn, Minist Educ, Key Lab Ocean Energy Utilizat & Energy Conservat, Dalian 116024, Peoples R China.

合写作者：

Liu, Shuyang,Chi, Yuan,Zhang, Qian,Zhang, Yi,Lv, Junchen,Li, Guanchu

发表时间：

2019-06-01

发表刊物：

THERMOCHIMICA ACTA

收录刊物：

EI、SCIE

文献类型：

J

卷号：

676

页面范围：

20-26

ISSN号：

0040-6031

关键字：

Density; Magnetic suspension balance; Carbon dioxide; Impurities; GERG-2008 EOS

摘要：

As a thermodynamic property, the density of CO2 mixtures plays an important role on carbon capture and storage. The densities of two CO2/N-2/O-2 ternary mixtures were measured at temperatures from (300.15-353.15) K and pressures from (5-18) MPa using a high-precision magnetic suspension balance. The temperature and pressure uncertainties were 0.01 K and 0.005 MPa, respectively. The density measurement uncertainty was estimated as 0.138 kg.m(-3). Impurities decreased the density of pure CO2 and the more the impurities were, the larger the reduction was. The densities of mixtures were calculated using GERG-2008 EOS and compared with experimental data. When the temperature and pressure were far away from the critical region, the discrepancy between the experimental data and GERG-2008 EOS calculations was small.