
教授 博士生导师 硕士生导师
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:材料科学与工程学院
学科:材料学
功能材料化学与化工
化学工程
办公地点:材料楼330办公室
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发布时间:2019-03-11
论文类型:会议论文
发表时间:2010-01-01
收录刊物:Scopus、CPCI-S、EI
页面范围:467-471
摘要:The effect of electromigration (EM) on the solid state interfacial reactions in line-type Cu/Sn/ENIG interconnect was investigated under the current density of 5.0x10(3) A/cm(2) at 150 degrees C for 100 h and 200 h. The Cu/Sn/ENIG specimens were also aged at the same temperature and durations for comparison. After soldering, Cu6Sn5 and Ni3Sn4 IMCs formed at the Cu/Sn and ENIG/Sn interfaces, respectively. During aging time, a thin Cu3Sn layer formed beneath the Cu6Sn5 at the Cu/Sn interface, and the original Ni3Sn4 transformed into (Cu, Ni)(6)Sn-5 IMC at the ENIG/Sn interface. A thin Ni3P film was detected at the ENIG/Sn interface after aging for 200 h. During EM, when the electrons flowed from the Cu side to the ENIG side, the type of interfacial IMCs kept unchanged at Cu/Sn interface for 100 h and 200h, while the origin Ni3Sn4 transformed into (Cu, Ni)(6)Sn-5 IMC at the ENIG/Sn interface for 100 h and 200h. When the electrons flowed toward the Cu side, high current density induced Ni-P consumption and EM-induced the formation of nearly all (Ni, Cu)(3)Sn-4 IMC in solder near the ENIG/Sn interface were observed. The EM-assisted crystallization of electroless Ni-P was more noticeable with increasing time, and a thin NiSnP layer formed on the thick Ni3P layer at the ENIG/Sn interface for 200 h. Little Ni was detected at the Cu/Sn interface when it acted as the anode side.