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基于氢键作用C_(60)/Bodipy超分子三重态光敏剂的设计及其光物理性质
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Indexed by:会议论文

Date of Publication:2016-09-01

Journal:第十四届固态化学与无机合成学术会议

Page Number:1

Key Words:三重态;氢键;C_(60)

Abstract:已报道的含有C_(60)的三重态光敏剂普遍是通过共价键将C_(60)与发色团连接,该方法合成工作量大,不利于光敏剂的筛选[1]。本文尝试将氢键超分子作用引入到光敏剂的设计当中[2]。氢键组装分子体系中的Bodipy部分可用作可见光吸收天线和单重态能量的给体,C_(60)部分则用作能量受体和电子自旋转换单元[8]。在甲苯中混合氢键给体和氢键受体即可实现氢键分子自组装,继而可以用稳态/瞬态光谱仪器对组装体系光物理性质进行研究。该方法可以高效地考察和筛选各种能量给体发色团。

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Alma Mater:Jilin University

Degree:Doctoral Degree

School/Department:School of Chemistry Engineering

Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)

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