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具有可见区强吸收的富勒烯衍生物的合成与应用
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Indexed by:会议论文

Date of Publication:2013-08-07

Page Number:96-96

Key Words:富勒烯 氟硼二吡咯染料 有机三重态敏化剂,光氧化

Abstract:三重光敏剂具有广泛的应用[1]。富勒烯具有很强的系间窜越能力,但是富勒烯在可见区的吸光能力很弱,不利于对可见光的利用。将氟硼二吡咯染料与富勒烯连接,制备出了具有可见区强吸收,同时具有长的三重激发态寿命的有机三重态敏化剂,并且将其用于敏化单线态氧实验,发现敏化单线态氧的能力与传统的铱络合物相比增强了19倍,与亚甲基蓝染料相比增强了1.7倍[2]。

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