Indexed by:期刊论文

Date of Publication:2012-09-21

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、EI、PubMed、Scopus

Volume:41

Issue:35

Page Number:10680-10689

ISSN No.:1477-9226

Abstract:Visible light-harvesting cyclometalated Ir(III) complexes with 3-(2-benzothiazoly)-7-diethylaminocoumarin as the C boolean AND N cyclometalation ligands were prepared. The ancillary N boolean AND N ligand is either 6-piperidine naphthalimide-phenanthroline (Ir-1) or 9-aminophenanthroline (Ir-3). Ir(ppy)(2)(Phen) was prepared as model complex (Ir-2). Ir-1 and Ir-3 show strong absorption of visible light (epsilon = 109 000 M-1 cm(-1) or 112 000 M-1 cm(-1) at 486 or 484 nm, respectively). All the complexes show room temperature phosphorescence with drastically different phosphorescence quantum yields (Phi(P) = 4.3%, 44.3% and 46.0% for Ir-1, Ir-2 and Ir-3, respectively). With steady state and time-resolved spectra, as well as DFT calculations, the T-1 excited states of Ir-1 and Ir-3 were proposed to be the (IL)-I-3 state, whereas the (MLCT)-M-3 state was proposed for Ir-2. Long-lived emissive triplet excited states (7.6 mu s and 54.5 mu s) were observed for Ir-1 and Ir-3, compared to the short T-1 excited state lifetime of Ir-2 (1.2 mu s). The complexes were used as triplet photosensitizers for triplet-triplet annihilation upconversion and upconversion quantum yields (Phi(UC)) of 19.3% and 12.7% were observed for Ir-1 and Ir-3, respectively. No upconversion was observed for Ir-2 under the same experimental conditions.