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Ruthenium(II) Polyimine Complexes with a Long-Lived (IL)-I-3 Excited State or a (MLCT)-M-3/(IL)-I-3 Equilibrium: Efficient Triplet Sensitizers for Low-Power Upconversion
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Indexed by:期刊论文

Date of Publication:2011-02-11

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:PubMed、Scopus、SCIE、EI

Volume:50

Issue:7

Page Number:1626-1629

ISSN No.:1433-7851

Key Words:photochemistry; pyrene; ruthenium; triplet excited states; upconversion

Abstract:Up, up, and away! The long-lived 3IL excited states of Ru II polyimine complexes were found to be more efficient in sensitizing upconversion based on triplet-triplet annihilation (TTA) and energy transfer (TTET) than the shorter-lived 3MLCT excited states (see picture). Upconversion occurs with an anti-Stokes shift of up to 0.77a eV. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Alma Mater:Jilin University

Degree:Doctoral Degree

School/Department:School of Chemistry Engineering

Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)

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