Indexed by:期刊论文
Date of Publication:2008-02-11
Journal:TETRAHEDRON
Included Journals:SCIE
Volume:64
Issue:7
Page Number:1309-1315
ISSN No.:0040-4020
Key Words:BINOL boronic acid; chiral recognition; enantioselective sensors; sugar alcohols
Abstract:A new chiral fluorescent BINOL boronic acid 1 has been synthesized. The chiral recognition properties of 1 are drastically different from BINOL boronic acid c. Sensor 1 shows improved enantioselectivity as well as chemoselectivity toward sugar alcohols, such as D-sorbitol and D-mannitol. The enantioselectivity of sensor 1 toward D-sorbitol (K-R/K-S) is 1:35 (pH 9.0), and the chemoselectivity for D-sorbitol/D-mannitol is 20:1. (c) 2007 Elsevier Ltd. All rights reserved.
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Alma Mater:Jilin University
Degree:Doctoral Degree
School/Department:School of Chemistry Engineering
Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)
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