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论文类型：期刊论文

发表时间：2016-02-01

发表刊物：CHEMICAL RECORD

收录刊物：SCIE、PubMed

卷号：16

期号：1

页面范围：173-188

ISSN号：1527-8999

关键字：chromophores; photochemistry; sensitizers; transition metals; triplet states

摘要：Transition-metal complex triplet photosensitizers are versatile compounds that have been widely used in photocatalysis, photovoltaics, photodynamic therapy (PDT) and triplet-triplet annihilation (TTA) upconversion. The principal photophysical processes in these applications are the intermolecular energy transfer or electron transfer. One of the major challenges facing these triplet photosensitizers is the short triplet-state lifetime, which is detrimental to the above-mentioned photophysical processes. In order to address this challenge, transition-metal complexes showing long-lived triplet excited states are highly desired. This review article summarizes the development of this fascinating area, including the molecular design rationales, the principal photophysical properties, and the applications of these complexes in PDT and TTA upconversion.