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论文类型：期刊论文

发表时间：2014-05-19

发表刊物：CHEMISTRY-A EUROPEAN JOURNAL

收录刊物：SCIE

卷号：20

期号：21

页面范围：6300-6308

ISSN号：0947-6539

关键字：aggregation; charge recombination; dyes; pigments; phenothiazine; solar cells

摘要：A series of simple phenothiazine-based dyes, namely, TP, EP, TTP, ETP, and EEP have been developed, in which the thiophene (T), ethylenedioxythiophene (E), their dimers, and mixtures are present to modulate dye aggregation, charge recombination, and dye regeneration for highly efficient dye-sensitized solar cell (DSSC) applications. Devices sensitized by the dyes TP and TTP display high power conversion efficiencies (PCEs) of 8.07 (J(sc)=15.2mAcm(-2), V-oc=0.783V, fill factor (FF)=0.679) and 7.87% (J(sc)=16.1mAcm(-2), V-oc=0.717V, FF=0.681), respectively; these were measured under simulated AM 1.5 sunlight in conjunction with the I-/I-3(-) redox couple. By replacing the T group with the E unit, EP-based DSSCs had a slightly lower PCE of 7.98% with a higher short-circuit photocurrent (J(sc)) of 16.7mAcm(-2). The dye ETP, with a mixture of E and T, had an even lower PCE of 5.62%. Specifically, the cell based on the dye EEP, with a dimer of E, had inferior J(sc) and V-oc values and corresponded to the lowest PCE of 2.24%. The results indicate that the photovoltaic performance can be finely modulated through structural engineering of the dyes. The selection of T analogues as donors can not only modulate light absorption and energy levels, but also have an impact on dye aggregation and interfacial charge recombination of electrons at the interface of titania, electrolytes, and/or oxidized dye molecules; this was demonstrated through DFT calculations, electrochemical impedance analysis, and transient photovoltage studies.