|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：有机化学. 应用化学. 物理化学
办公地点：西部校区E座208房间
联系方式：0411－84986236
电子邮箱：zhaojzh@dlut.edu.cn
BODIPY-based photosensitizers with intense visible light harvesting ability and high O-1(2) quantum yield in aqueous solution
点击次数：
论文类型：期刊论文
发表时间：2014-10-03
发表刊物：RSC ADVANCES
收录刊物：SCIE、EI、Scopus
卷号：4
期号：93
页面范围：51349-51352
ISSN号：2046-2069
摘要：A novel method to enhance the singlet oxygen quantum yield of photosensitizers in aqueous solution has been developed by introducing an electron-withdrawing group into BODIPY. B-2 was prepared based on this method and shows intense light harvesting ability (epsilon = 6.8 x 10(4) M-1 cm(-1) at 643 nm)and high O-1(2) quantum yield in aqueous solution (phi = 0.21). B-2 has been successfully used as an O-1(2) sensitizer for the photo-oxidation of 1,5-dihydroxynaphthalene. This method substantially improves the photooxidation capability and photostability of O-1(2) sensitizers in aqueous solution.
上一条：Broadband Visible-Light-Harvesting trans-Bis(alkylphosphine) Platinum(II)-Alkynyl Complexes with Singlet Energy Transfer between BODIPY and Naphthalene Diimide Ligands
下一条：The effect of the regioisomeric naphthalimide acetylide ligands on the photophysical properties of (NN)-N-boolean AND Pt(II) bisacetylide complexes