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论文类型：期刊论文

发表时间：2013-02-01

发表刊物：DYES AND PIGMENTS

收录刊物：SCIE、EI

卷号：96

期号：2

页面范围：449-458

ISSN号：0143-7208

关键字：Fullerene; Naphthalenediimide; Photosensitizer; Triplet state; Triplet photosensitizer; Upconversion

摘要：Two naphthalenediimide (NDI)-C-60 dyads that show strong absorption of visible light were prepared as heavy atom-free organic triplet photosensitizers. Alkylamino substituted NDI was used as the light-harvesting antennas and the C-60 unit was used as spin converter for the intersystem crossing (ISC) from singlet excited state to triplet excited state. Upon visible light photoexcitation, triplet excited states of the dyads are populated (lifetime is up to 90.1 mu s). Nanosecond time-resolved transient difference absorption spectroscopy indicated that the triplet excited state of the dyads is localized on either the NDI or the C-60 unit. As a proof of concept, the dyads are used as heavy-atom-free organic triplet photosensitizers for triplet-triplet annihilation based upconversion. C-60-organic chromophore dyads can be used as a general molecular structural motif of heavy-atom-free organic triplet photosensitizers, for which the photophysical properties can be readily changed by using different light-harvesting antennas, and the ISC property of these dyads is predictable. (C) 2012 Elsevier Ltd. All rights reserved.