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论文类型：期刊论文

发表时间：2013-05-01

发表刊物：PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES

收录刊物：SCIE、PubMed、Scopus

卷号：12

期号：5

页面范围：872-882

ISSN号：1474-905X

摘要：A series of ketocoumarin compounds were prepared as heavy atom-free triplet photosensitizers. The photophysical properties of the compounds were studied with steady state and time-resolved spectroscopy. The compounds show absorption in the visible spectral region (molar absorption coefficients are up to epsilon = 136 000 M-1 cm(-1) at 448 nm) and long-lived triplet excited states (tau(T) = 199.7 mu s) upon visible light photoexcitation. The compounds were used as triplet photosensitizers for singlet oxygen (O-1(2))-mediated photooxidation of 1,5-dihydroxylnaphthalene (DHN) to produce juglone. O-1(2) quantum yields of these compounds were determined in the range of 0.28-0.48. The ketocoumarins were also used as triplet photosensitizers for triplet-triplet annihilation (TTA) upconversion, and upconversion quantum yields up to 11.3% were observed. The results are useful for preparation of heavy atom-free triplet photosensitizers and for their application in photocatalysis and TTA upconversion.