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论文类型：期刊论文

发表时间：2012-12-01

发表刊物：DYES AND PIGMENTS

收录刊物：Scopus、SCIE、EI

卷号：95

期号：3

页面范围：732-742

ISSN号：0143-7208

关键字：Coumarin; Density functional theory; Geometry relaxation; Photochemistry; Photophysics; Stokes shift

摘要：A series of new fluorophores with a fused coumarin framework were prepared. The dyes show red-shifted and enhanced absorption compared to the model compound, 7-hydroxycoumarin. The new coumarin bearing a 4-dimethylaminophenylacetylide group, shows absorption at 389 nm (epsilon = 14,300 M-1 cm(-1)), compared to the model compound which shows blue shifted absorption bands (epsilon = 11,500 M-1 cm(-1) at 320 nm). The emission of the new coumarin bearing a 4-dimethylaminophenylacetylide group is remarkably red-shifted (lambda(em) = 555 nm) compared to the model compound (lambda(em) = 356 nm). The fluorescence quantum yields of the new coumarins are increased up to ca. 9-fold compared to the model compound. The Stokes shifts (84 nm-166 nm) are also much larger than that of the model compound. TDDFT calculations show that the fused coumarins undergo significant geometry relaxation upon photoexcitation, which is responsible for the large Stokes shift. Population of the triplet excited state was observed for the bromo-functionalized coumarin. (c) 2012 Elsevier Ltd. All rights reserved.