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论文类型：期刊论文

发表时间：2012-10-14

发表刊物：JOURNAL OF MATERIALS CHEMISTRY

收录刊物：SCIE、EI、Scopus

卷号：22

期号：38

页面范围：20273-20283

ISSN号：0959-9428

摘要：The synthesis of visible light-harvesting C-60-bodipy dyads (bodipy boron-dipyrromethene), and the study of the photophysical properties and the application of dyads as heavy-atom free organic triplet photosensitizers for triplet-triplet annihilation (TTA) based upconversion, are reported. By attaching carbazole units to the p-core of the bodipy chromophore via an ethynyl linker, the absorption wavelength of the antenna in the dyads is readily tuned from 504 nm for the unsubstituted bodipy, to 538 nm (one carbazole unit, epsilon = 61 800 M-1 cm(-1)) and 597 nm (two carbazole units, epsilon = 58 200 M-1 cm(-1)). Upon photoexcitation at 538 nm (dyad C-1) or 597 nm (dyad C-2), intramolecular energy transfer from the antenna to the C-60 unit occurs, and as a result, the singlet excited state of the C-60 unit is populated. Subsequently, with the intrinsic intersystem crossing (ISC) of C-60, the triplet excited state of the C-60 unit is produced (tau(T) up to 24.5 mu s). Thus, without the need for any heavy atoms, the triplet excited state of the dyads was populated upon visible light excitation. The population of the C-60-localized triplet excited state of the dyads was confirmed by nanosecond time-resolved transient difference absorption spectra and spin density analysis. The dyads were used as triplet photosensitizers for TTA upconversion and upconversion quantum yields of up to 2.9% were observed.