|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：有机化学. 应用化学. 物理化学
办公地点：西部校区E座208房间
联系方式：0411－84986236
电子邮箱：zhaojzh@dlut.edu.cn
扫描关注
Ruthenium(II) Polyimine Complexes with a Long-Lived (IL)-I-3 Excited State or a (MLCT)-M-3/(IL)-I-3 Equilibrium: Efficient Triplet Sensitizers for Low-Power Upconversion
点击次数：
论文类型：期刊论文
发表时间：2011-02-11
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物：PubMed、Scopus、SCIE、EI
卷号：50
期号：7
页面范围：1626-1629
ISSN号：1433-7851
关键字：photochemistry; pyrene; ruthenium; triplet excited states; upconversion
摘要：Up, up, and away! The long-lived 3IL excited states of Ru II polyimine complexes were found to be more efficient in sensitizing upconversion based on triplet-triplet annihilation (TTA) and energy transfer (TTET) than the shorter-lived 3MLCT excited states (see picture). Upconversion occurs with an anti-Stokes shift of up to 0.77a eV. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.